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B51-14 (R2019) – Boiler, pressure vessel, and pressure piping code

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ISO 5993:1979

ISO 5993:1979 Sodium hydroxide for industrial use – Determination of mercury content – Flameless atomic absorption spectrometric method

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Description

Covers a method applicable to liquid or solid products having mercury contents greater than 0,02 mg/kg. The principle of determination is based on oxidation of the mercury contained in a test portion to mercury(II) ions by potassium permanganate in the presence of sulphuric acid, reduction of the excess oxidant by hydroxylammonium chloride, reduction of the mercury(II) ions to mercury by tin(II) chloride, entrainment of the mercury in air or nitrogen, passage of the gaseous mixture through a measuring cell, and measurement of the absorption at a wavelength of 253,7 nm.

Edition

1

Published Date

1979-09-01

Status

PUBLISHED

Pages

6

Language Detail Icon

English

Format Secure Icon

Secure PDF

Abstract

Covers a method applicable to liquid or solid products having mercury contents greater than 0,02 mg/kg. The principle of determination is based on oxidation of the mercury contained in a test portion to mercury(II) ions by potassium permanganate in the presence of sulphuric acid, reduction of the excess oxidant by hydroxylammonium chloride, reduction of the mercury(II) ions to mercury by tin(II) chloride, entrainment of the mercury in air or nitrogen, passage of the gaseous mixture through a measuring cell, and measurement of the absorption at a wavelength of 253,7 nm.

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